Solid inclusions have been used by gemologists as a means of determining origin. While there is a great deal of overlap from one source to another, there are also important differences. For example, while apatite has been identified in sapphire from Madagascar, Myanmar and Sri Lanka, apatite has never been identified in sapphire from Kashmir. Thus the purpose of this article is to give a full listing of solid inclusions in gem corundums from around the world, with each occurrence fully referenced. This is provided with the goal of making origin determination of ruby and sapphire more accurate.
It is a capital mistake to theorize before one has data. Insensibly one begins to twist facts to suit theories, instead of theories to suit facts.
Sherlock Holmes, "A Scandal in Bohemia"
Inclusions in Ruby & Sapphire (Corundum)
Corundums may contain a rich variety of solid inclusions. These are often related to type of geologic process of formation. Thus a knowledge of basic geologic principles is useful in understanding the inclusion types.
Geology of Corundum Deposits
Gem quality ruby and sapphire deposits around the world are mainly of two types: metamorphic origin, where corundum occurs associated with marble. These include:
Metamorphic processes
- Amphibolite: Australia (Hart's Range), Greenland, Kenya, Madagascar, Malawi, Mozambique, Tanzania (Longido, Winza)
- Biotite: Madagascar (Sahambano)
- Cordieritite: Madagascar (Iankaroka)
- Gneiss: India (Mysore)
- Granulite: Sri Lanka
- Mafic-Ultramafic: Tanzania (Longido)
- Marble: Afghanistan, China (Yunnan), Kenya (Pamreso), Macedonia (Prilep), Myanmar, Nepal, Pakistan, Tajikistan, Tanzania (Mahenge, Morogoro), Vietnam (Yen Bai, Quy Chau)
- Migmatite: Tanzania (Morogoro)
- Pegmatite: India (Kashmir): Pegmatite associated with actinolite-tremolite lenses
- Kenya (Mangari), Tanzania (Umba): Desilicated pegmatites cutting or in contact with serpentinite
- Skarn: Madagascar (Andranondambo)
In addition, there are alluvial gem corundum deposits thought to have formed via metamorphism where the nature of the original host rocks is unknown. These include:
- Madagascar (Ilakaka area), Sri Lanka, Tanzania (Tunduru)
Magmatic processes
Corundums have also been found in magmatic rocks. These include:
- Alkali basalts: Australia, Cambodia, Cameroon, China, Ethiopia, France, Kenya, Israel, Madagascar (north), New Zealand, Nigeria, Rwanda, Scotland, Thailand, Vietnam (Dak Nong)
- Lamprophyre: Yogo Gulch, MT (USA)
- Syenite: Kenya (Garba Tula)
There are also alluvial gem corundum deposits associated with magmatic processes where the nature of the original host rocks is unknown. These include:
- USA: Dry Cottonwood, Missouri River, Rock Creek, MT
Ages of corundum-bearing rocks
Corundum bearing rocks generally fall into three broad categories, as follows:
Pan-African orogeny: 730–450 million years ago (Ma)
Deposits in East Africa, Madagascar, Sri Lanka and southern India generally formed 730–550 million years ago, associated with the Pan-African orogeny, where eastern and western Gondwana collided.
Himalayan orogeny: 45–5 Ma
The Himalayan orogenic event occurred 25–5 million years ago (Giuliani & Fallick et al., 2017), where the Indian subcontinent collided with and was subducted under the Asia plate, producing the greatest mountain chain on Earth.
Cenozoic alkali basalt extrusions: 65–1 Ma
Corundum is also associated with alkali basalts (65–1 million years ago). While forming deeper in the earth, corundum crystals were brought to the surface by basalt eruptions. These include:
- Australia, Cambodia, Cameroon, China, France, Kenya, Israel, Madagascar (north), New Zealand, Nigeria, Rwanda, Thailand, Vietnam.
The oldest corundums have been found in Greenland, and are believed to be approx. 2.7 billion years old.
Inclusion Types
Primary cavities
Corundum often plays host to primary cavities (negative crystals). These are often filled with liquid and gaseous CO2, and may also contain solids such as diaspore and/or graphite. This combination is particularly common in corundums from Sri Lanka.
Secondary Cavities
Corndum contains a wide variety of secondary fluid inclusions. These are often filled with liquid and gaseous CO2.
Solids
Corundum is host to a rich variety of solids. These can be placed into the following categories according to a scheme first developed by Gübelin (1973):
- Protogenetic: Solids that formed before the host
- Syngenetic: Solids that formed simultaneously with the host
- Epigenetic: Solids that formed after the host. These form through a process of exsolution.
Secondary (Exsolved) Solids
Exsolution is the “unmixing” of a solid solution. At high temperatures, crystals have more defects, and thus are better able to absorb impurities. As the crystal cools, defects are reduced. This may force impurities to crystallize out. But because of the constraints placed on their movement by the solid host, impurity atoms are unable to travel large distances. Therefore, rather than forming large crystals, they migrate short distances to form multitudes of tiny needles, plates and particles, along the directions in the host where space permits.
A number of exsolved minerals have been found in corundum. These include:
- Boehmite
- Diaspore
- Gibbsite
- Hematite
- Ilmenite
- Kaolinite
- Rutile
Traces of these exsolved minerals often show up in the infrared spectra. Some of these minerals may also be present as epigenetic deposits in fissures.
Growth Features
Growth features can be divided into two broad categories, as follows:
- Twinning
- Growth zoning
Twinning
Twinning in corundum can occur at the time of growth. These are known as growth twins, when, as a crystal is growing, it begins growing in a new direction. These typically occur as single planes only, rather than being repeated throughout the crystal.
If certain types of crystals are subjected to mechanical stress or pressure at any time after their formation, the bonds between planes of atoms may be broken and the planes “slip” or “glide” across one another into a twinned position, with new bonds immediately formed (if the pressure is too great, however, the crystal just breaks). This type of twinning often occurs repeatedly throughout a crystal (and is termed ‘polysynthetic twinning’), and due to the pressure that produced it, such crystals often contain many cracks (as well as healed cracks). Examples: Rhombohedral twinning in corundum, quartz (amethyst) and calcite.
Growth Zoning
During a crystal’s growth, coloring agents may not be available in consistent amounts. The result is a layered appearance of lighter and darker lines (or bands) which follow the external surfaces of the crystal. This is similar to the growth rings of trees, except that with single crystals, the external surfaces are flat and meet at specific angles. Thus the growth lines of single crystals will always be straight (never curved, unless one looks in directions not parallel to the faces along which they formed). They may form parallel to any of the faces that are, or were, present while the crystal was growing.
Table 1: Solids in Ruby & Sapphire (Corundum)
Solid Inclusion Type | Corundum Origin | Earliest Reference |
Aluminite Group – Monoclinic or Triclinic
|
|
Zwaan & Buter et al., 2015 |
Amphibole Group (includes hornblende) – Monoclinic or Orthorhombic
|
Pargasite
General Amphibole
|
Barthoux, 1933 |
Anatase – Tetragonal – TiO2 – Polymorph of Akaogiite, Brookite, Rutile, TiO2 II, UM1991-08-O:Ti |
|
Khoi & Sutthirat et al., 2011 |
Andalusite – Orthorhombic – Al2(SiO4)O – Polymorph of Kyanite, Sillimanite |
|
Hughes (in press) |
Anhydrite – Orthorhombic – CaSO4 |
|
Smith & Dunaigre, 2001 |
Apatite Group – Hexagonal
|
Chlorapatite
Fluorapatite
General Apatite
|
Chlorapatite: Schubnel (1967) Fluorapatite: Keller & Koivula et al., 1985 General: Gübelin, 1969 |
Aragonite Group – Orthorhombic
|
|
Vertriest, 2015 |
Baddeleyite Group – Monoclinic
|
|
Guo et al., 1996 Gübelin & Peretti, 1997 |
Baryte (Barite) Group – Orthorhombic
|
|
Zwaan & Buter et al., 2015 |
Böhmite (Boehmite) – Orthorhombic – AlO(OH) – Polymorph of Diaspore |
|
Sahama & Lehtinen et al., 1973 |
Brookite – Orthorhombic – TiO2 – Polymorph of Akaogiite, Anatase, Riesite, Rutile, TiO2 II, UM1991-08-O:Ti |
|
Gübelin & Koivula, 1986 |
Calcite Group – Hexagonal or Trigonal |
Calcite
Magnesite
|
Calcite: Gübelin, 1953 Magnesite: Thirangoon, K., 2009 |
Carbon – Amorphous – C |
|
Zwaan & Buter et al., 2015 |
Catapleiite – Monoclinic – Na2Zr(Si3O9) · 2H2O – Polymorph of Gaidonnayite |
|
Thirangoon, K., 2009 |
Chalcopyrite Group – Tetragonal
|
|
Gübelin, 1973 |
Chlorite Group – Mostly monoclinic (also triclinic or orthorhombic) – A5-6T4Z18 Clinochlore – Mg5Al(AlSi3O10)(OH)8 – Monoclinic |
|
Gübelin, 1982 Clinochlore – Hughes, Hyperion Database, 2020 |
Columbite Group – Orthorhombic
|
Columbite-(Fe)
Tantalite–(Mn)
|
Niobite – Gübelin, 1973 Columbite – Guo & Reilly et al., 1996 Tantalite – Pardieu & Sangsawong et al., 2014 |
Cordierite (iolite) – Orthorhombic – (Mg,Fe)2Al3(AlSi5O18) |
|
Thirangoon, 2009 |
Cosalite – Orthorhombic – Pb2Bi2S5 |
|
Thirangoon, K., 2009 |
Cristobalite – Tetragonal – SiO2 – Polymorph of Coesite, Keatite, Mogánite, Quartz, Seifertite, Stishovite, Tridymite |
|
Zwaan & Buter et al., 2015 |
Dawsonite – Orthorhombic – NaAlCO3(OH)2 |
|
Giuliani & Dubessy et al., 2018 |
Diaspore Group – Orthorhombic |
Diaspore
Goethite
|
Diaspore – Smith, 1995 Goethite – Gübelin, 1992 |
Dolomite Group – Trigonal |
Ankerite
Dolomite
|
Brückl, 1937 |
Epidote Supergroup – Monoclinic – {A12+A22+M13+M23+M33+}(Si2O7)(SiO4)O(OH)
|
Allenite
Clinozoisite
Epidote
|
Allenite
Clinozoisite
Epidote
|
Euxenite Group – Orthorhombic or Amorphous
|
|
Guo & O’Reilly et al., 1996 |
Feldspar Group – Monoclinic or Triclinic
|
|
Gübelin, 1969 |
Feldspathoid Group – Tetragonal, Hexagonal, Trigonal, Triclinic
|
|
Saminpanya & Sutherland, 2011 |
Fergusonite – Tetragonal – YNbO4 |
|
Gübelin, 1973 |
Fluorite Group – Isometric
|
|
Peretti & Schmetzer et al., 1995 |
Garnet Group – Isometric – X3Z2(SiO4)3
|
Almandine
Pyrope
|
Brückl, 1937; Gübelin, 1948; Du Toit & Charoensrithanakul et al., 1995 |
Gibbsite – Monoclinic – Al(OH)3 – Polymorph of Bayerite, Doyleite, Nordstrandite, UM1990-28-OHF:Al |
|
Zwaan & Buter et al., 2015 |
Glass – Amorphous |
|
Gübelin & Koivula, 1986 |
Grandidierite – Orthorhombic – (Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2 |
|
Hain & Hughes, 2019 |
Graphite – Hexagonal – C – Polomorph of Chaoite, Diamond, Lonsdaleite |
|
Brückl, 1937 |
Halite Group – Isometric
|
|
Khoi & Sutthirat, C. et al., 2011 |
Hematite Group – Trigonal
|
Corundum
Eskolaite
Hematite
|
Hematite – Barthoux, 1933 Corundum – Gübelin, 1940b Eskolaite – Zhou, 2017 |
Humite Group – Orthorhombic or Monoclinic
|
|
Barthoux, 1933 |
Huntite – Trigonal – CaMg3(CO3)4 |
|
Vertriest & Manorotkul et al., 2015 |
Ilmenite Group – Trigonal
|
|
Moon & Phillips, 1984 |
Kaolinite-Serpentine Group – Hexagonal, Trigonal, Orthorhombic, Monoclinic, Triclinic
|
|
Sangsawong & Vertriest et al., 2017 |
Kyanite – Triclinic – Al2(SiO4)O – Polymorph of Andalusite, Sillimanite |
|
Pardieu & Sangsawong et al., 2013 |
Marcasite Group – Orthorhombic |
|
Bowersox & Foord et al., 2000 |
Mica Group – Monoclinic
|
Biotite
Margarite
Muscovite
Phlogopite
Trilithionite
General Mica
|
Gübelin, 1940b, 1982 |
|
|
Saeseaw & Sangsawong et al., 2017 |
Monazite Group – Monoclinic
|
Cheralite
|
Gübelin, 1973 |
Nahcolite – Monoclinic – NaHCO3 |
|
Zwaan & Buter et al., 2015 |
Nordstrandite – Triclinic – Al(OH)3 – Polymorph of Bayerite, Doyleite, Gibbsite, UM1990-28-OHF:Al |
|
Kane & McClure et al., 1991 |
Olivine Group – Orthorhombic – Fe22+SiO4 to Mg2SiO4
|
|
Gübelin, 1971 |
Pentlandite Group – Isometric or Tetragonal
|
|
Coenraads, 1992 |
Pyrite Group – Isometric |
|
Barthoux, 1933 |
Pyrochlore Supergroup – Isometric – A2-mD2X6-wZ1-n (betafite; discredited)
|
|
Gübelin, 1969 |
Pyroxene Group – Orthorhombic or Monoclinic – ABSi2O6
|
Augite (including Fassaite)
Diopside
General Pyroxene
|
Gübelin, 1971 |
Pyrrhotite Group – Hexagonal, Monoclinic or Triclinic
|
|
Gübelin, 1971 |
Quartz – Trigonal – SiO2 |
|
Promwongnan & Sutthirat, 2019b |
Rhabdophane Group – Hexagonal
|
|
Guo & O’Reilly et al., 1996 |
Rutile Group – Tetragonal |
|
Tschermak, 1878; Barthoux, 1933 |
Samarskite Group – Orthorhombic or Monoclinic
|
|
Guo & O’Reilly, 1996 |
Sapphirine Group – Monoclinic or Triclinic
|
|
Koivula & Fryer, 1987 |
Scapolite Group – Tetragonal – Na4Al3Si9O24Cl to Ca4Al6Si6O24CO3 |
|
Kammerling & Scarratt et al., 1994 |
Sillimanite – Orthorhombic – Al2(SiO4)O5 – Polymorph of Andalusite, Kyanite |
|
Thirangoon, K., 2009 |
Smectite Group – Monoclinic
|
|
Zwaan, 1974 |
Sodalite Group – Isometric or Orthorhombic
|
|
Renfro & Pardieu, 2012 |
Sphalerite Group – Isometric
|
|
Gübelin, 1973 |
Spinel Supergroup – Isometric |
Chromite
Gahnite (including Gahnospinel)
Hercynite
Magnetite
Spinel
General Spinel Group
|
Brückl, 1937 |
Staurolite Group – Monoclinic
|
|
Hughes, E.B., 2019 |
Sulfur (Sulphur) Group – Orthorhombic or Monoclinic
|
|
Fritsch & Rossman, 1990 |
Tialite – Al2TiO5 |
|
Panjikar & Panjikar, 2016 |
Titanite Group – Monoclinic or Triclinic
|
|
Barthoux, 1933 |
Topaz – Orthorhombic – Al2(SiO4)(F,OH)2 |
|
Zwaan & Buter et al., 2015 |
Tourmaline Group – Trigonal – Complex borosilicates |
|
Gübelin, 1973 |
Uraninite Group – Isometric
|
Thorianite
|
Uraninite: Gübelin, 1973 Thorianite: Gübelin & Koivula, 2008 |
Vesuvianite Group – Tetragonal
|
|
Renfro & Koivula, 2017 |
Wollastonite Group – Triclinic
|
|
Gübelin & Koivula, 2008 |
Xenotime Group – Tetragonal
|
|
Gübelin & Koivula, 2008 |
Zeolite Group – All systems possible
|
|
Gübelin & Koivula, 1986 |
Zircon Group – Tetragonal |
Thorite
|
Zircon: Gübelin, 1940b Thorite: Gübelin, 1973 |
Zirconolite – Orthorhombic – CaZrTi2O7 |
|
Peretti, A., Peretti, F. et al., 2008 |
Zirkelite – Isometric – (Ti,Ca,Zr)O2-x |
|
Gübelin & Koivula, 2008 |
Zoisite – Orthorhombic – Ca2Al3[Si2O7][SiO4]O(OH) – Dimorph of Clinozoisite |
|
Zwaan & Buter et al., 2015 |
References & further reading
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About the authors
E. Billie Hughes visited her first gem mine (in Thailand) at age two and by age four had visited three major sapphire localities in Montana. A 2011 graduate of UCLA, she qualified as a Fellow of the Gemmological Association of Great Britain (FGA) in 2013. An award winning photographer and photomicrographer, she has won prizes in the Nikon Small World and Gem-A competitions, among others. Her writing and images have been featured in books, magazines, and online by Forbes, Vogue, National Geographic, and more. In 2019 the Accredited Gemologists Association awarded her their Gemological Research Grant. Billie is a sought-after lecturer and has spoken around the world to groups including Cartier and Van Cleef & Arpels. In 2020 Van Cleef & Arpels’ L’École School of Jewellery Arts staged exhibitions of her photomicrographs in Paris and Hong Kong.
Richard W. Hughes is one of the world’s foremost experts on ruby and sapphire. The author of many books and over 170 articles, his writings and photographs have appeared in a diverse range of publications, and he has received numerous industry awards. Co-winner of the 2004 Edward J. Gübelin Most Valuable Article Award from Gems & Gemology magazine, the following year he was awarded a Richard T. Liddicoat Journalism Award from the American Gem Society. In 2010, he received the Antonio C. Bonanno Award for Excellence in Gemology from the Accredited Gemologists Association. The Association Française de Gemmologie (AFG) in 2013 named Richard as one of the Fifty most important figures that have shaped the history of gems since antiquity. In 2016, Richard was awarded a visiting professorship at Shanghai's Tongji University. 2017 saw the publication of Richard and his wife and daughter's Ruby & Sapphire • A Gemologist's Guide, arguably the most complete book ever published on a single gem species and the culmination of four decades of work in gemology. In 2018, Richard was named Photographer of the Year by the Gem-A, recognizing his photo of a jade-trading market in China, while in 2020, he was elected to the board of directors of the Accredited Gemologists Association and was appointed to the editorial review board of Gems & Gemology and The Australian Gemmologist magazine. In 2022, Richard published Jade • A Gemologist's Guide, while 2024 brought Broken Bangle • The Blunder-Besmirched History of Jade Nomenclature.
Notes
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